
Name: Dr Tamim Darwish
Position: Research Organic Chemist
Phone: +61 2 97179080
Email: tamim.darwish@ansto.gov.au
Role at ANSTO
Tamim is a research chemist in the Chemical Deuteration team at the National Deuteration Facility (NDF) at ANSTO. His responsibilities lie primarily in contributing to establishment of the capability to synthesize and charaterise organic molecules labelled with deuterium. He is involved in small and large scale syntheses of deuterated organic and polymeric molecules for the new OPAL research reactor neutron scattering, NMR and other techniques, as well as for external users. Tamim has background in organic / organometallic synthesis and advanced NMR characterisation utilities.
Expertise: Mulitnuclear NMR Spectroscopy, Organic/Organometallic Synthesis, Photochemistry, C-H Bond Activation, Photochromism, Self-Assembled Monolayer on Silicon, X-ray Reflectometry.
Qualifications & Achievements:
Key Publications:
Ball, G.E.; Brookes, C.M.; Cowan, A.J.; Darwish, T.A.; George, M.W.; Kawanami, H.K.; Portius, P. and Rourke, J.P., "A delicate balance of complexation vs. activation of alkanes interacting with [Re(Cp)(CO)(PF3)] with studies with NMR and time-resolved IR Spectroscopy" Proc. Natl. Acad.Sci. U.S.A. 2007, 104, 6927.
Lawes, D.J.; Darwish T.A.; Clark, T.; Harper, J.B. and Ball, G.E., "A Rhenium-Cyclohexane Complex with Preferential Binding of Axial C-H Bonds: A Probe into the Relative Ability of C-H, C-D and C-C Bonds as Hyperconjugative Electron Donors?" Angew. Chew. Int. Ed. 2006, 45, 4486.
Ball, G.E.; Darwish, T.A.; Geftakis, S.; George, M.W.; Lawes, D.J.; Portius, P. and Rouke, J.P., "Characterization of an Organometallic Xenon Complex Using NMR and IR Spectroscopy" Proc. Natl.Acad. Sci. U.S.A. 2005, 102,1853.
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